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If they aren't in the middle of an adrenaline rush or on drugs
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No gun will stop someone with a single shot reliably, one shot from a .25 to the central nervous system will stop someone, in their tracks, high or sober. This is the same with any gun.
Once read a story about a cop that shot someone high on drugs 6 times with a .41 magnum revolver and that didn't even stop him.
Shot placement > Caliber.